ISSN 0132-3547
Scientific-technical journal
ENVIRONMENTAL
PROTECTION
IN OIL AND GAS COMPLEX
published
since 1993
November
2014
¹ 11
12
issues per year
CONTENÒS
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Shmakov A.V., Yeletskiy B.D.,
Akinin M.V., Shnurman I.G.
«Ecological improvement of the Sea of Azov» – the priority Programme of LLC
«NK «Priazovneft» (p. 5-9)
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Korpakova I.G., Pavlenko L.F.,
Larin A.A., Skrypnik G.V., Klimenko T.L., Anokhina N.S., Evseeva A.I., Ekilik
V.S., Temerdashev Z.A.
Hydrocarbons in the Sea of Azov water and bottom sediments within the limits
of the licensed area of LLC «NK «Priazovneft» (p. 10-17)
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Korpakova I.G., Afanas’yev D.F., Tsybul’skiy
I.E., Barabashin T.O., Belova L.V., Naletova L.Yu., Bychkova M.V. Special features of biological
communities progression in the south-eastern part of the Sea of Azov in 2013 (p. 18-25)
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Korpakova I.G., Larin A.A.,
Korablina I.V., Malkhasyan E.A., Temerdashev Z.A. The content of heavy metals in the water and
bottom sediments of the licensed site of LLC «NK «Priazovneft» in the Sea of
Azov in 2013 (p. 25-29)
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Korpakova I.G., Larin A.A.,
Korotkova L.I., Koropenko E.O., Syundyukova T.I., Zubtsova I.A., Mandrykina
M.A., Temerdashev Z.A. The
peculiarities of pollution by resistant organochlorine pesticides and
polychlorbiphenyls found in the licensed area of LLC «NK «Priazovneft» in the
south-eastern part of the Sea of Azov in 2013 (p. 29-32)
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Pogorelov A.V., Antonenko M.V.,
Boiko E.S., Fyodorova S.I., Yeletskiy Yu.B. Research into the components of the coastal zone of the
Sea of Azov by the airborne laser scanning data (Verbyanaya Spit area) (p. 33-39)
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Litvinskaya S.A. Functions, significance and
saving of the Kuban river delta firth-flooded intertidal landscapes (p. 40-46)
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Nagalevskiy Yu.Ya., Nagalevskiy
E.Yu., Yeletskiy Yu.B. Kulikovo-Kurchanskaya
system of limans. Hydrography and conditions of water cycle (p. 46-51)
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Temerdashev Z.A., Shapoval E.V., Kolychev
I.A., Yeletskiy B.D., Korpakova I.G. Research into tricyclic condensed arenes origin in
marketable petrols and assessment of their contents in their combustion
products (p. 52-56)
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Artyukhin Yu.V., Fedorova S.I. Estimation of stability of
wave-suppression facility and Verbyanaya Spit by geomorfological monitoring
data (p. 56-64)
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Information on the articles (p. 65-70)
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Information on the articles
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«ECOLOGICAL IMPROVEMENT OF THE SEA OF AZOV» –
THE PRIORITY PROGRAMME
OF LLC «NK «PRIAZOVNEFT» (p. 5)
Shmakov A.V., Yeletskiy B.D.,
Akinin M.V., Shnurman I.G.
LLC "NK «Priazovneft»"
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UDC 628.394.1:574.5(262.54)
HYDROCARBONS IN THE SEA
OF AZOV WATER AND BOTTOM SEDIMENTS
WITHIN THE LIMITS OF THE
LICENSED AREA OF LLC «NK «PRIAZOVNEFT»
(p. 10)
Irina Korpakova, Dr. Sc. (Biology),
Prof.,
Liliya Pavlenko, PhD (Chemistry),
Andrey Larin, PhD (Chemistry),
Galina Skrypnik, PhD (Chemistry),
Tat’yana Klimenko,
Natal’ya Anokhina,
Alla Evseeva,
Viktoriya Ekilik
FSUE «Azov Fisheries Research
Institute» (FSUE «AzNIIRKH»)
21v, Beregovaya str.,
Rostov-on-Don, 344002, Russia,
tel./fax: 8(863) 262-05-05,
e-mail: riasfp@aaanet.ru
Zaual Temerdashev, Dr. Sc.(Chemistry),
Prof.
FSBEI HPE «Kuban State University »
149, Stavropol’skaya str.,
Krasnodar, 350040, Russia,
tel./fax:
8(861)219-95-72/219-95-71,
e-mail: temza@kubsu.ru
Results
of studies on the hydrocarbon pollution of the Sea of Azov south-eastern part
conducted in 2013 within the limits of the licensed area of LLC «NK
«Priazovneft» are presented. Distribution is considered of oil products
(hydrocarbons and resins) in the water and bottom sediments of the site in
question including the sea and the coastal area and the Kurchanskiy liman.
The origin of paraffin and polycyclic aromatic hydrocarbons found in the
marine ecosystem has been characterized. The distribution of paraffin
hydrocarbons in the water column is characterized by predominance of either low
molecular C15–C18 alkanes or even-numbered alkanes (C16–C26).
In the bottom sediments predominance of C17 and high molecular
odd-numbered n-alkanes (C27, C29, C31 and C33)
is noted. In water PAH are dominated by naphthalene, 2-methylnaphthalene,
phenanthrene, fluoranthene and chrysene, while in bottom sediments only
chrysene is observed in great concentrations.
Key
words: the Sea of Azov; licensed site of LLC «NK «Priazovneft»; oil
pollution; origin of hydrocarbons.
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UDC 574.5(262.54)
SPECIAL FEATURES OF
BIOLOGICAL COMMUNITIES PROGRESSION
IN THE SOUTH-EASTERN
PART OF THE SEA OF AZOV IN 2013 (p. 18)
Irina Korpakova, Dr. Sc. (Biology),
Prof.,
Dmitriy Afanas’yev, PhD (Biology),
Igor’ Tsybul’skiy, PhD (Biology),
Timofey Barabashin, PhD (Biology),
Lyudmila Belova,
Larisa Naletova,
Marina Bychkova
FSUE «Azov Fisheries Research
Institute» (FSUE «AzNIIRKH»)
21v, Beregovaya str., Rostov-on-Don,
344002, Russia,
tel./fax: 8(863) 262-05-05,
e-mail: riasfp@aaanet.ru
Results
of hydrobiological studies conducted in summer 2013 in the licensed area of LLC «NK «Priazovneft» in the south-eastern part of the Sea of Azov and
in the Kurchanskiy liman are presented. The structure and composition of
biological communities have been characterized including data on bacterio-,
phyto- and zooplankton, zooneuston, bacterio- and zoobenthos. Comparative
analysis of the structure and distribution of hydrobiological communities in
the sea and coastal part of the Sea of Azov and the Temryuk Bay as well as
the Kurchanskiy liman has been made. According to obtained data for the last
few years the relationship and occurrence of some individual groups of plankton
and benthos organisms is being changed which testifies about succession
changes of structures of investigated biological communities. Data of
interannual dynamics of ecosystems basic links are being discussed.
Key words: the Sea of Azov; hydrobiological communities; plankton;
benthos.
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UDC 628.394.1:574.5(262.54)
THE CONTENT OF HEAVY
METALS
IN THE WATER AND BOTTOM SEDIMENTS
OF THE LICENSED SITE
OF LLC «NK «PRIAZOVNEFT»
IN THE SEA OF AZOV IN 2013 (p. 25)
Irina Korpakova, Dr. Sc. (Biology),
Prof.,
Andrey Larin, PhD (Chemistry),
Irina Korablina,
Elizaveta Malkhasyan
FSUE «Azov Fisheries Research Institute»
(FSUE «AzNIIRKH»)
21v, Beregovaya str.,
Rostov-on-Don, 344002, Russia,
tel./fax: 8 (863) 262-05-05,
e-mail: riasfp@aaanet.ru
Zaual Temerdashev, Dr. Sc. (Chemistry),
Prof.
FSBEI HPE «Kuban State University »
149, Stavropol’skaya str., Rostov-on-Don,
344002, Russia,
tel./fax: 8(861) 219-95-72,
e-mail: temza@kubsu.ru
Results
are presented on the research into heavy metal pollution that were conducted
at the licensed site of LLC «NK «Priazovneft» in the south-eastern Sea of
Azov in 2013. The level of water and bottom sediments pollution has been
assessed according to Russian and international standards. Specific
distribution of heavy metals in the water and bottom sediments of the marine
and coastal zones of the region under consideration as well as in Kurchanskiy
liman is shown and compared with the data obtained earlier. The total water
pollution is assessed by the sum of averaged maximum permissible
concentrations, and the pollution of bottom sediments is assessed by the sum
of averaged concentrations typical of different types of bottom sediments of
the Sea of Azov, long-term observations have allowed us to collect these
data.
Key words: pollution; concentration; the Sea of Azov; licensed site
of LLC «NK «Priazovneft»; heavy metals.
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UDC 628.394.17:632.95
THE PECULIARITIES OF
POLLUTION
BY RESISTANT
ORGANOCHLORINE PESTICIDES
AND POLYCHLORBIPHENYLS
FOUND IN THE LICENSED AREA
OF LLC «NK «PRIAZOVNEFT»
IN THE SOUTH-EASTERN PART
OF THE SEA OF AZOV IN
2013 (p. 29)
Irina Korpakova, Dr. Sc. (Biology),
Prof.,
Andrey Larin, PhD (Chemistry),
Liliya Korotkova, PhD (Chemistry),
Elena Koropenko,
Tamara Syundyukova,
Inna Zubtsova,
Marina Mandrykina
FSUE «Azov Fisheries Research
Institute» (FSUE «AzNIIRKH»)
21v, Beregovaya str.,
Rostov-on-Don, 344002, Russia,
tel./fax: 8(863)262-05-05,
e-mail: riasfp@aaanet.ru
Zaual Temerdashev, Dr. Sc.(Chemistry),
Prof.
FSBEI HPE «Kuban State University »
149, Stavropol’skaya str.,
Rostov-on-Don, 344002, Russia,
tel./fax:8 (861)219-95-72,
e-mail: temza@kubsu.ru
Pollution
of the water and bottom sediments at the Temryuk-Akhtarsk licensed site of
LLC «NK «Priazovneft» in the Sea of Azov by organochlorine pesticides and
polychlorinated biphenyls in 2013 has been studied and the results are
presented. There, in the samples of water and bottom sediments, n,n'-DDE,
n,n'-DDD and n,n'-DDT were found. In the water of Kurchansky liman and in the
bottom sediments in the whole water area of the Temryuk-Akhtarsk licensed
area polychlorbiphenils were not found. From defined congeners of PCB in the
water thickness of the water area studied. The most persistent and dangerous
high-chlorinated polybiphenyls (penta- and hexachlorbiphenyls) were
identified, among them dioxine-type congeners were found.
Key words: the Sea of Azov; licensed site of LLC «NK «Priazovneft»;
pollution; organochlorine pesticides; polychlorbiphenyls.
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UDC 551.435.3
RESEARCH INTO THE
COMPONENTS OF THE COASTAL ZONE
OF THE SEA OF AZOV BY
THE AIRBORNE LASER SCANNING DATA
(VERBYANAYA SPIT AREA)
(p. 33)
Anatoliy Pogorelov, Dr. Sc. (Geography),
Prof.,
Mikhail Antonenko, PhD (Geography),
Evgeniy Boiko, PhD (Geography)
FSBEI HPE «Kuban State University »
149, Stavropol’skaya str.,
Krasnodar, 350040, Russia,
tel./fax: 8(861)219-95-80,
e-mail: pogorelov@nm.ru
Svetlana Fyodorova, PhD (Tech.)
LLC «Science-design Center
«Beregozashchita»
74, Promyshlennaya str., Krasnodar,
350002, Russia,
tål./fax: 8(861)253-80-34,
e-mail: kbznik@mail.ru
Yuriy Eletskiy, PhD (Geography)
Southern Scientific Centre of
Russian Academy of Science
149, Stavropol’skaya str.,
Krasnodar, 350040, Russia,
tel./fax: 8 (861)219-95-01
In
the Verbyanaya Spit area (the Sea of Azov) in an attempt to create
large-scale cartographic base and subsequent thematic mapping of the
geographical environment components airborne laser scanning and aerial
photography were conducted. Airborne laser scanning data formed the basis of
a comprehensive study of the coastal zone components. Methodical research
apparatus includes receiving and processing technology of laser reflection
points, constructing high-precision digital elevation model and raster
surfaces. Mosaic of aerial photographs is converted into a format mosaic – a
geometrically correct image of the terrain. Set of high-precision digital
surface models and thematic raster images obtained for specific dates, allows
to analyze the dynamic adjustment of components of the coastal zone
(shoreline, beach, shore dam with surge prism).
Key words: the Sea of Azov; coastal zone; morphology; laser
scanning; monitoring; 3D-modeling; digital terrain model.
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UDC 581.9 (470.620)
FUNCTIONS, SIGNIFICANCE AND
SAVING OF THE KUBAN RIVER DELTA
FIRTH-FLOODED INTERTIDAL
LANDSCAPES (p. 40)
Svetlana Litvinskaya, Dr. Sc. (Biology)
FSBEI HPE «Kuban State University »
149, Stavropol’skaya str.,
Krasnodar, 350040, Russia,
tel.: 8(918)999-00-40,
e-mail: Litvinski@yandex.ru
Information
about the functions that are performed in the biosphere by birth-flooded
complexes is given. Ichthyological, ornithological and floristical
significance of Kuban delta is disclosed. The firth-flooded landscapes are a
source of aesthetic and artistic inspiration, they provide the shelter to
wild animals and form the basis of important local traditions of social,
economic and cultural character. Wetlands provide conditions for the development
of a number of species of wildlife. The flooded estuaries are important and
necessary to ensure the health, welfare and safety of people. The negative
human impact on the various components of the firth-flooded natural complex
is considered. A number of management solutions for sustainable development
of the firth-flooded complex «Kuban Delta» are proposed. The necessity of
Kuban river delta wetlands preserving and selection of protected area are
grounded.
Key words: Kuban river delta; firth-flooded complex; functions;
significance; anthropogenic disturbances; protected area; zoning.
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UDC 536.5(470.620)
KULIKOVO-KURCHANSKAYA
SYSTEM OF LIMANS. HYDROGRAPHY AND CONDITIONS
OF WATER CYCLE (p. 46)
Yuriy Nagalevskiy, PhD (Geography),
Edward Nagalevskiy, PhD (Geography)
FSBEI HPE «Kuban State University »
149, Stavropol’skaya str., Krasnodar, 350040, Russia,
tel./fax: +7 (961) 219-95-80,
e-mail: fizgeografia@kubsu.ru
Yuriy Yeletskiy, PhD (Geography)
Southern Scientific Centre of
Russian Academy of Science
149, Stavropol’skaya str.,
Krasnodar, 350040, Russia,
tel./fax: +7(861)219-95-01.
The
article considers the Kulikovo-Kurchanskaya group of limans, which is the receiver
of waste water from irrigated rice fields. Correction to the hydrological
regime subject to receipt both by river and sea waters is made. Morphometry
of this group basic limans is considered and water balance of Kulikovskiy and
Kurganskiy limans is calculated. The project of improving exchange of water
between the limans by deepening channels and canal systems is developed.
Key
words: hydrography; system of estuaries; morphometry; water change; water
balance; monitoring.
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UDC 543.545
RESEARCH INTO TRICYCLIC
CONDENSED ARENES
IN MARKETABLE PETROLS
AND ASSESSMENT OF THEIR CONTENTS
IN THEIR COMBUSTION
PRODUCTS (p. 52)
Zaual Temerdashev, Dr. Sc. (Chemistry),
Prof.,
Elena Shapoval, post-graduate student,
Igor’ Kolychev, PhD (Chemistry)
FSBEI HPE «Kuban State University »
149, Stavropol’skaya str.,
Krasnodar, 350040, Russia,
tel./fax: 8(861)
219-95-71/219-95-72,
e-mail: temza@kubsu.ru
Boris Yeletskiy, Dr. Sc.(Biology)
LLC «NK «Priazovneft»
99, Kirova str., Krasnodar, 350000,
Russia,
tel.: 8(861) 255-07-78,
e-mail: elezkiy@pn.kubannet.ru
Irina Korpakova, Dr. Sc. (Biology),
Prof.,
FSUE «Azov Fisheries Research Institute»
(FSUE «AzNIIRKH»)
21v, Beregovaya str.,
Rostov-on-Don, 344002, Russia,
tel.: 8(863) 262-44-29/262-05-05,
e-mail: korpakova@ice-group.ru
The
problems of presence and determination of polycyclic aromatic hydrocarbons
(PAHs) in automobile marketable petrols and their combustion products are
discussed. Their origin is investigated and the quantitative determination of
their content in explored samples is performed by chromatography-mass
spectrometry. It is determined that there is a complex of tricyclic condensed
arenes such as phenanthrene, anthracene and methyl-derivations in all samples
of petrols. The established ratios of phenanthrene to 2-methylphenanthrene
and 3-methylphenanthrene are 0,4…1,1 for all samples, and the ratios of
phenanthrene to 9-methylphenanthrene and 1-methylphenanthrene – 3,3…5,8 and
1,8…4,1 accordingly, the ratios of phenanthrene to anthracene are over the
range from 10,8 to 56,5. It is shown that the ratios of phenanthrenes are
permanent for petrols ÀÈ-92 and ÀÈ-95 belonging to the same
manufacturer and practically don´t change for all examined samples.
That fact can be used as identification feature of petrol sample. The
researches have shown the presence of PAHs including phenanthrene, anthracene
and methyl-derivations in automobile exhausts. The abundant quantity of PAHs
is found out in exhausts of an automobile that is not equipped with a
catalyst converter, the minimal quantity – in exhausts of automobiles with a
catalytic afterburner system.
Key words: tricyclic condensed arenes; petrols; catalytic reforming;
catalytic converter; automobile exhausts; chromatography-mass spectrometry.
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UDC 551.482.6(262.54)
ESTIMATION OF STABILITY
OF WAVE-SUPPRESSION
FACILITY AND VERBYANAYA SPIT
BY GEOMORFOLOGICAL
MONITORING DATA (p. 56)
Yuriy Artyukhin, PhD (Geography)
tel.: 8(861)327-74-23.
e-mail: arty-yeisk@mail.ru
Svetlana Fedorova, PhD (Tech.)
tel.: 8(861)055-57-69.
e-mail: kbznik@mail.ru
LLC «Scientific-Project Center
«Beregozaschita»
127, Ñhapaevà
str., Krasnodar, 350000, Russia
Observations
on the condition of shore protection dam with operating road are being performed
after its construction in 2007. The dam is built within the framework of
investment project, called upon to provide safety of water-marsh area, in
according with the Ramsar Convention. Monitoring included the research into
the realignment of dam, beach and underwater slope of Verbyanaya spit up to 5 m depth, the analysis of beach and bottom sediments changeability. Levelling and batimetric
measurements were carried out in accordance with the technical requirements
once a year, on 15 transverse profiles, bolted by bench marks on the
territory. The analysis of obtained data has shown that hydrotecnical
structures have stopped the erosion of the windward coast of the spit and
disappearance of drifts in limans and lagoons water area. The dam basically maintains
the size provided by the project. The Verbyanaya spit underwater slope is
subjected to space-temporary realignment, controlled by the complex of
hydrometeorological and lithological factors.
Key words: sea shore of the Kuban river delta; Verbyanaya spit;
accumulative form; beach; wave-suppression dam; deformation of facility,
beach and underwater slope; dynamic balance; beach and bottom sediments.
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